MARYVILLE UNIVERSITY COURSE SYLLABUS
 COURSE INFORMATION
: Semester/Year: Spring 2008
 CHEM 204 01 Organic Chemistry II
 PROFESSOR: Dr. Frank Stary Credit Hours: 4
 MEETING TIME: Lecture CHEM 204 01 MW 8-9:15 a.m.
 Lab 1 CHEM 204 L1 M 12:15 a.m.-2:55 p.m.
 Lab 2 CHEM 204 L2 W 12:15 a.m.-2:55 p.m.

 Lab 3 CHEM 204 L3 F 12:15 a.m.-2:55 p.m.
 MEETING PLACE: Lecture R 2318
 Laboratory K 2117
 OFFICE HOURS: M-Th 7-8 a.m. T Th 8-9:15 a.m. R 3306
 OFFICE PHONE: 529-9425 leave message EMAIL: fstary@maryville.edu
 OBJECTIVE: To introduce the student to electrophilic aromatic substitution, spectroscopy and structure, alcohols, ethers and epoxides, aldehydes and ketones, carboxylic acids, carbanions, amines, phenols, monosaccharides and amino acids and proteins. Assigned problems give the student experience necessary to understand organic chemistry and the tests given in the course. There is an emphasis on reactions and some synthesis in the lectures and the examinations.
 PROCEDURE: The course consists of 2-1/2 hours of lecture and 2-1/2 hours of lab per week.
 TECHNOLOGY: Digital melting point apparatus, refractometer, Microscale glassware kits, analytical balances, gas chromatography, IR spectrometer, automatic pipettes, top-loader balances, calculator, theory of [proton NMR, mass spectrometry, IR, UV-VIS, ESR, HPLC], magnetic hot plates
 Grade Distribution                                                                 Grading Scale (%)
 
Final Exam 20%                                                                       100-90 A
 Midterm Exam 30%                                                                 90-86.67 A-
 Lab 20%                                                                                  86.67-83.33 B+
 Hourly Exams 20% Drop lowest one-no makeup's                      83.33-80 B
 Homework 10% Drop lowest two                                             80-76.67 B-
                                                                                                76.67-73.33 C+
                                                                                                73.33-70 C
                                                                                                70-60 C-
                                                                                                60-50 D
  NOTE: This syllabus is subject to change at the discretion of the professor.
 COURSE OUTLINE
: ORGANIC CHEMISTRY CHEM 204 01 DR. STARY
 TEXTBOOKS: Morrison and Boyd Organic Chemistry 6th Edition
 Study Guide to Accompany Morrison and Boyd 6th Edition (Optional Answer Book)
 Mayo, Pike, Butcher Microscale Organic Laboratory 4th Edition
 Bound Lab Notebook, Safety Glasses, Calculator (rarely used)
 HOMEWORK:
 Chapter Topics and Problems
13 Cyclic Aliphatic Compounds 1(skip names)ij, 2(skip names)abceg to qsw to aa, 3ak, 16 (skip names)cjl, 18ab
15 Electrophilic Aromatic Substitution 1abfj, 4a, 5c, 15bdkm, 16be
17 Spectroscopy and Structure 1a-e, 2a-d, 21, 22
18 Aldehydes and Ketones Nucleophilic Addition 2abeho, 3behjklmop, 5ad, 7abcf, 13a
19 Carboxylic Acids 1 C1-5, 3abc, 4ab, 6egkq, 11(skip names)acfmn, 20
21 Carbanions I Aldol and Claisen Condensations 1abde, 3(skip names)bcehi, 4ab, 9
22 Amines I. Preparation and Physical Properties 2befijm, 4abcef, 5ac, 6ab, 7, 8
24 Phenols 1bcdfgij, 3cde, 4c(para)el, 5degikmtuvxyz
34 Carbohydrates I. Monosaccharides 1(skip names)bcdekmor, stable ring form of glucose, aldose sugar tree, aldoketoses, PFST
36 Proteins and Nucleic Acids Molecular Biology 1abef,10
 LABS: Diels-Alder Reaction 14, The Perkin Reaction 18, Aldol Reaction 20, Williamson Synthesis of Ethers 22B, Synthesis of Cyclic Carboxylic Anhydrides: Succinic Anhydride 25A, Heterocyclic Ring Synthesis: Dicoumarol 3Badv, Halogenation: Electrophilic Aromatic Substitution to Yield 4-Bromoacetanilide 28, Nitration: 2,5-Dichloronitrobenzene 29A, Nucleophilic Aromatic Substitution: 2,4-Dinitrophenylthiocyanate 30, Hypochlorite Oxidation of Methyl Ketones by the Haloform Reaction: Benzoic Acid 34A.
One week after the experiment is performed, the lab report is submitted for grading by the professor. The format, shown on page 29 of the lab textbook gives the student practice in writing technical reports.
EXPECTED LECTURE SCHEDULE: CHEM 204-01 Spring 2008
14 Jan
16 Jan Cha 13 due
21 Jan Cha 15 due
23 Jan
28 Jan Exam 1 Chas 13 & 15
30 Jan
04 Feb Cha 17 due
06 Feb Cha 18 due
11 Feb
13 Feb Exam 2 Chas 17-18
18 Feb
20 Feb Cha 19 due
25 Feb Cha 21 due
27 Feb
10 Mar Exam 3 Chas 19 &21
12 Mar
17 Mar Midterm Exam Chas 13, 15, 17-19, 21
19 Mar
24 Mar Cha 22 due
26 Mar Cha 24 due
31 Mar
02 Apr Exam 4 Chas 22 & 24
07 Apr
09 Apr Cha 34 due
14 Apr Cha 36 due
16 Apr
21 Apr Exam 5 Chas 34 & 36
23 Apr
28 Apr Final Exam Chas. 22, 24, 34, 36
 Do not
buy airplane tickets departing before 6pm on 28 April 2008.

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